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Intrinsically chiral ferronematic liquid crystals

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arxiv 2112.11887 v1 pith:RISG2ECF submitted 2021-12-22 cond-mat.soft cond-mat.mtrl-sci

Intrinsically chiral ferronematic liquid crystals

classification cond-mat.soft cond-mat.mtrl-sci
keywords chiralchainlateralphasephasesachiralalkylcenter
verification ladder T0 review T1 audit T2 compute T3 formal T4 reserved
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Strongly dipolar mesogenic compounds with a chiral center located in a lateral alkyl chain were synthesized, and shown to form the ferroelectric nematic phase. The presence of molecular chirality induced a helical structure in both the N and NF phases, but with opposite helix sense in the two phases. The relaxation frequency of the polar fluctuations was found to be lower for the chiral NF phase than for its achiral, non-branched counterpart with the same lateral chain length.

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