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Electronic structure of MgB₂: X-ray emission and absorption studies

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arxiv cond-mat/0103487 v3 pith:P7OMKY64 submitted 2001-03-23 cond-mat.supr-con cond-mat.mtrl-sci

Electronic structure of MgB₂: X-ray emission and absorption studies

classification cond-mat.supr-con cond-mat.mtrl-sci
keywords x-rayemissionspectraabsorptionbandssigmaaccountagreement
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Measurements of x-ray emission and absorption spectra of the constituents of MgB$_2$ are presented. The results obtained are in good agreement with calculated x-ray spectra, with dipole matrix elements taken into account. The comparison of x-ray emission spectra of graphite, AlB$_2$, and MgB$_2$ in the binding energy scale supports the idea of charge transfer from $\sigma$ to $\pi$ bands, which creates holes at the top of the bonding $\sigma$ bands and drives the high-T$_c$

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