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Comment on "Electron-phonon coupling in two-dimensional silicene and germanene"

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arxiv 1707.03075 v1 pith:K4DPPX2X submitted 2017-07-10 cond-mat.mtrl-sci

Comment on "Electron-phonon coupling in two-dimensional silicene and germanene"

classification cond-mat.mtrl-sci
keywords phononsilicenecouplinggraphenecalculationsdfpte-phfrozen
verification ladder T0 review T1 audit T2 compute T3 formal T4 reserved
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In their work, Yan et al. [Phys. Rev. B 88, 121403 (2013)] employing density functional perturbation theory (DFPT) calculations, demonstrate that silicene and germanene show weaker Kohn anomalies in the $\Gamma$-$E_g$ and $K$-$A_1$ phonon modes, compared to graphene. Furthermore, they compute the electron phonon (e-ph) coupling matrix elements using the frozen phonon approach and found that in silicene the average e-ph coupling matrix-element square over the Fermi surface, $\langle g_{{\bf q}\nu}^2\rangle_{F}$, is about 50 % of those in graphene, but in germanene is weaker and nearly negligible. However, Yan et al. argues that the smaller Fermi velocity in silicene compensates the reduced $\langle g_{{\bf q}\nu}^2\rangle_{F}$, leading to phonon linewidths ($\gamma_{{\bf q}\nu}$) slightly larger than those in graphene. In this Comment, we show that the DFPT and the frozen phonon results of Yan et al. for silicene are inconsistent. Additionally, we have evaluated the e-ph coupling using direct DFPT calculations, analytical relations, and frozen phonon calculations, and we found systematically that $\langle g_{{\bf q}\nu}^2\rangle_{F}$ and $\gamma_{{\bf q}\nu}$ in silicene are one order of magnitude smaller than in graphene, in contrast to the conclusions of Yan et al.

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