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Adsorbate Interactions of CO Chemisorbed on Pt(111)

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arxiv cond-mat/9712026 v1 pith:E35J4TUV submitted 1997-12-02 cond-mat

Adsorbate Interactions of CO Chemisorbed on Pt(111)

R. Brako , D. Sokcevic (R. Boskovic Institute , Zagreb , Croatia) This is my paper
classification cond-mat
keywords interactionobservedpt--coadsorbateagreementcalculatedchemisorbedcoordinates
verification ladder T0 review T1 audit T2 compute T3 formal T4 reserved
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We show that the observed repulsive interaction between CO molecules on the Pt(111) surface can be explained by the coupling of the Pt--CO separation with Pt-Pt coordinates in the substrate. The observed long range of the interaction and the non-monotonic distance dependence are reproduced. The magnitude of the multiphonon decay of the Pt--CO vibration calculated in this model is also in agreement with experiment.

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