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Superconductivity in metal rich Li-Pd-B ternary Boride

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arxiv cond-mat/0402232 v1 pith:NE6I4N34 submitted 2004-02-09 cond-mat.supr-con cond-mat.mtrl-sci

Superconductivity in metal rich Li-Pd-B ternary Boride

K. Togano , P. Badica , Y. Nakamori , S. Orimo , H. Takeya , K. Hirata This is my paper
classification cond-mat.supr-con cond-mat.mtrl-sci
keywords metalsuperconductivityrichternarycompoundli-pd-balkalineboride
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8K superconductivity was observed in the metal rich Li-Pd-B ternary system. Structural, microstructural, electrical and magnetic investigations for various compositions proved that Li2Pd3B compound, which has a cubic structure composed of distorted Pd6B octahedrons, is responsible for the superconductivity. This is the first observation of superconductivity in metal rich ternary borides containing alkaline metal and Pd as a late transition metal. The compound prepared by arc melting has high density, is stable in the air and has an upper critical field, Hc2(0), of 6T.

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