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Radiative association of atomic and ionic carbon

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arxiv 1909.09620 v1 pith:U2MEWF2P submitted 2019-09-11 physics.atom-ph astro-ph.SR

Radiative association of atomic and ionic carbon

classification physics.atom-ph astro-ph.SR
keywords associationprocessradiativeavailablecalculationsdatamolecularnumber
verification ladder T0 review T1 audit T2 compute T3 formal T4 reserved
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We present calculated cross sections and rate coefficients for the formation of the dicarbon cation (C$_2^+$) by the radiative association process in collisions of a C$(^3P)$ atom and a C$^+(^2P^o)$ ion. Molecular structure calculations for a number of low-lying doublet and quartet states of C$_2^+$ are used to obtain the potential energy surfaces and transition dipole moments coupling the states of interest, substantially increasing the available molecular data for C$_2^+$. Using a quantum-mechanical method, we explore a number of allowed transitions and determine those contributing to the radiative association process. The calculations extend the available data for this process down to the temperature of 100 K, where the rate coefficient is found to be about $2\times 10^{-18}$ cm$^3$/s. We provide analytical fits suitable for incorporation into astrochemical reaction databases.

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