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Collective excitation of electric dipole on molecular dimer in organic dimer-Mott insulator

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arxiv 1210.2878 v3 pith:3YGOBS4F submitted 2012-10-10 cond-mat.str-el

Collective excitation of electric dipole on molecular dimer in organic dimer-Mott insulator

classification cond-mat.str-el
keywords electricbandcollectivedimer-mottdipoleexcitationinsulatorkappa-
verification ladder T0 review T1 audit T2 compute T3 formal T4 reserved
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The terahertz (THz) response in 10-100 cm^-1 was investigated in an organic dimer-Mott (DM) insulator kappa-(ET)_2Cu_2(CN)_3 that exhibits a relaxor-like dielectric anomaly. 30 cm^-1 band in the optical conductivity was attributable to collective excitation of the intra-dimer electric dipoles which are formed by an electron correlation. We succeeded in observing photoinduced enhancement of this 30 cm^-1 band, reflecting the growth of the electric dipole cluster in the DM phase. Such optical responses in kappa-(ET)_2Cu_2(CN)_3 reflect instability near the boundary between the DM-ferroelectric charge ordered phases.

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