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Crystal Structure and Physical Properties of Mg6Cu16Si7-type M6Ni16Si7, for M = Mg, Sc, Ti, Nb, and Ta

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arxiv 0708.0179 v2 pith:K2KS7M6Y submitted 2007-08-01 cond-mat.supr-con cond-mat.mtrl-sci

Crystal Structure and Physical Properties of Mg6Cu16Si7-type M6Ni16Si7, for M = Mg, Sc, Ti, Nb, and Ta

classification cond-mat.supr-con cond-mat.mtrl-sci
keywords compoundsm6ni16si7bandscrystalmeasurementsparamagnetismreportedstructure
verification ladder T0 review T1 audit T2 compute T3 formal T4 reserved
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Five compounds were investigated for magnetic character and superconductivity, all with non-magnetic nickel and band structures containing flat bands and steep bands. The syntheses and crystal structures, refined by powder X-ray diffraction, are reported for M6Ni16Si7, where M = Mg, Sc, Ti, Nb, and Ta. All compounds form in the Mg6Cu16Si7 structure type. Resistance measurements are also reported on M6Ni16Si7 (M = Mg, Sc, Ti, and Nb) down to 0.3 K, with all four showing metallic conductivity. No superconductivity is observed. Magnetization measurements for all compounds reveal essentially temperature independent paramagnetism, with a tendency toward more enhanced low temperature paramagnetism for the cases of Mg6Ni16Si7 and Sc6Ni16Si7.

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