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Absence of Local Fluctuating Dimers in Superconducting Ir_(1-x)(Pt,Rh)_xTe₂

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arxiv 1801.00050 v1 pith:JIXD3YER submitted 2017-12-29 cond-mat.supr-con

Absence of Local Fluctuating Dimers in Superconducting Ir_(1-x)(Pt,Rh)_xTe₂

classification cond-mat.supr-con
keywords dimerlocalabsenceassociateddimersfluctuationsmodulatedproposed
verification ladder T0 review T1 audit T2 compute T3 formal T4 reserved
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The compound IrTe2 is known to exhibit a transition to a modulated state featuring Ir-Ir dimers, with large associated atomic displacements. Partial substitution of Pt or Rh for Ir destabilizes the modulated structure and induces superconductivity. It has been proposed that quantum critical dimer fluctuations might be associated with the superconductivity. Here we test for such local dimer correlations and demonstrate their absence. X-ray pair distribution function approach reveals that the local structure of Ir0.95Pt0.05Te2 and Ir0.8Rh0.2Te2 dichalcogenide superconductors with compositions just past the dimer/superconductor boundary is explained well by a dimer-free model down to 10 K, ruling out the possibility of there being nanoscale dimer fluctuations in this regime. This is inconsistent with the proposed quantum-critical-point-like interplay of the dimer state and

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